Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes

نویسندگان

  • F. Farzaneh Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of Iran
  • L. Hamidipour Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of Iran
چکیده مقاله:

Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or  ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions. 

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mn-metal organic framework as heterogenous catalyst for oxidation of alkanes and alkenes

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عنوان ژورنال

دوره 27  شماره 1

صفحات  31- 37

تاریخ انتشار 2016-01-01

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